mCPBA Oxidation of Acetyllycoctonine and Its New Products
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- Shen Xiang-Li
- Department of Chemistry of Medicinal Natural Products, West China College of Pharmacy, Sichuan University
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- Wang Feng-Peng
- Department of Chemistry of Medicinal Natural Products, West China College of Pharmacy, Sichuan University
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Treatment of a lycoctonine-type alkaloid acetyllycoctonine (4) with mCPBA at room temperature led to acetyllycoctonine N-oxide (5) as the major product together with other interesting compounds 6—12 as the minor products, which were derived from oxidation involving the nitrogen atom and Cope elimination as well as Polonovski-like fragmentation. All of those new compounds (5—12) were fully characterized.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 53 (3), 267-270, 2005
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390282679147946880
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- NII論文ID
- 10016652478
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 7268172
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- PubMed
- 15744095
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
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- 使用不可