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- OKADA MASASHI
- Tokyo Biochemical Research Institute
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- SAITO YUKIO
- Tokyo Biochemical Research Institute
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説明
From the stereochemical point of view, sodium borohydide reduction of the four possible 14-deoxy-15-oxocardenolides (14β, 17β; 14β, 17α; 14α, 17β; 14α, 17α) wasinvestigated. The 15-oxo group in the 14β-cardenolides (C/D cis) was reduced to give 15α-hydroxy epimer as the main product, while predominant formation of 15β-hydroxy epimer was observed with the 14α-cardenolides (C/D trans), irrespective of the configurationof the butenolide at C-17.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 21 (2), 388-393, 1973
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390282679148577664
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- NII論文ID
- 130003767058
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- ISSN
- 13475223
- 00092363
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可