Amino acids and peptides. XV. A new synthesis of .ALPHA.-amino acids by amination of .ALPHA.-metalated carboxylic acids.
書誌事項
- 公開日
- 1975
- DOI
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- 10.1248/cpb.23.167
- 公開者
- 公益社団法人 日本薬学会
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説明
Amination of α-lithiated carboxylic acid salts was investigated using isovaleric acid mainly. Methoxyamine bearing a proper electronic character was the best aminating reagent, as shown in Table I. Several α-amino acids, e.g., valine, leucine, methionine, phenylalanine, and α-phenylglycine, were prepared by this new method, summarized in Table II. The synthesis of two new aminating reagents, 3, 5-dinitromesitoxyamine and 2-tetrahydropyranyloxyamine were described.
収録刊行物
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- ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ
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ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ 23 (1), 167-172, 1975
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390282679150232064
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- NII論文ID
- 110003621658
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可