Synthesis of a Carbon Analogue of Scytonemin

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  • Mukai Chisato
    Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
  • Arima Katsuya
    Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
  • Hirata Shuichi
    Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University
  • Yasuda Shigeo
    Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University

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The synthesis of a carbon analogue of scytonemin was accomplished on the basis of molybdenum-mediated intramolecular double Pauson–Khand type reaction of bis(allenyne), followed by the double aldol condensation of the formed double Pauson–Khand type adduct.

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