Contribution of Cu<SUP>+</SUP> Ions Dissolved in AgBr to the Transport Properties
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- Saito Masatoshi
- Graduate School of Science and Technology, Niigata University
Bibliographic Information
- Other Title
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- Contribution of Cu+ Ions Dissolved in AgBr to the Transport Properties
- Contribution of Cu + Ions Dissolved in
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Abstract
The electrical conductivities and transport numbers of the solid solution (AgxCu1−x)Br have been measured as a function of temperature and composition. An attempt to determine the partial conductivities and activation energies for mobile ions is made from these results. The estimated enthalpies of formation and migration for Ag+ and Cu+ ions show an exponential decrease with increasing amount of Cu+ into AgBr lattice. The lowering is attributable to the lattice expansion by the occupation of Cu+ at the interstitial sites. The effect of exponential decrease in the formation enthalpy is to allow a rapid growth in the concentration of interstitials around the composition of χ\simeq0.85. This result is consistent with structural data derived by X-ray diffraction.
Journal
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 60 (10), 3415-3425, 1991
THE PHYSICAL SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390282679153429888
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- NII Article ID
- 110001977086
- 210000096336
- 130003740837
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- NII Book ID
- AA00704814
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- BIBCODE
- 1991JPSJ...60.3415S
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- COI
- 1:CAS:528:DyaK38Xhtlyguw%3D%3D
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- ISSN
- 13474073
- 00319015
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- NDL BIB ID
- 3740091
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed