Structures of molten silver halides by neutron diffraction
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- Inui Masanori
- College of General Education, Kyushu University
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- Takeda Shin’ichi
- College of General Education, Kyushu University
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- Shirakawa Yoshiyuki
- Graduate School of Science and Technology, Niigata University
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- Tamaki Shigeru
- Department of Physics, Faculty of Science, Niigata University
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- Waseda Yoshio
- Research Institute of Mineral Dressing and Metallurgy (SENKEN), Tohoku University
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- Yamaguchi Yasuo
- Institute for Materials Research, Tohoku University
書誌事項
- タイトル別名
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- Structural Study of Molten Silver Halides by Neutron Diffraction
- Structural Study of Molten Silver Halid
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説明
The Structure factors of molten AgCl, AgBr and AgI have been obtained by neutron scattering measurements at two different temperatures in order to investigate the local structure and its temperature dependence. The partial structural parameters such as a partial coordination number and an inter ionic distance have been determined by curve fitting analysis. Molten silver halides are found to have tetrahedral coordination of the local order near the melting points. The local order for molten AgCl and AgBr is broken with increasing temperature, while that for molten AgI is preserved even at high temperature. This suggests that the bonding in molten AgI has more covalent character than that in molten AgCl and AgBr.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 60 (9), 3025-3031, 1991
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390282679154167168
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- NII論文ID
- 110001977263
- 130003901235
- 210000096276
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- NII書誌ID
- AA00704814
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- BIBCODE
- 1991JPSJ...60.3025I
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- COI
- 1:CAS:528:DyaK3MXmtFGnsbo%3D
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 3740159
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDLサーチ
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- 使用不可