Rhodium-Catalyzed (Perfluoroalkyl)olefination of Acetanilides Leading to Perfluoroalkylated Aromatics

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  • Harada Kohei
    Graduate School of Pharmaceutical Sciences, The University of Tokyo
  • Tezuka Noriyuki
    Graduate School of Pharmaceutical Sciences, The University of Tokyo
  • Hirano Keiichi
    Graduate School of Pharmaceutical Sciences, The University of Tokyo
  • Miyamoto Kazunori
    Graduate School of Pharmaceutical Sciences, The University of Tokyo
  • Saito Tatsuo
    Graduate School of Pharmaceutical Sciences, The University of Tokyo
  • Uchiyama Masanobu
    Graduate School of Pharmaceutical Sciences, The University of Tokyo Elements Chemistry Laboratory, RIKEN Center for Sustainable Resource Science, RIKEN

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Abstract

<p>We have developed an efficient Rh-catalyzed (perfluoroalkyl)olefination reaction of acetanilides, which provides a versatile synthetic entry to a range of perfluoroalkylated compounds.</p>

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