Indirect Transitions in the Fundamental Absorption Edges of ZrS2 and HfS2

  • Terashima Koichi
    Department of Pure and Applied Sciences, College of Arts and Sciences, University of Tokyo
  • Imai Isamu
    Department of Pure and Applied Sciences, College of Arts and Sciences, University of Tokyo

書誌事項

タイトル別名
  • Indirect Transitions in the Fundamental Absorption Edges of ZrS<SUB>2</SUB> and HfS<SUB>2</SUB>
  • Indirect Transitions in the Fundamental
  • Indirect Transitions in the Fundamental Absorption Edges of ZrS<sub>2</sub>and HfS<sub>2</sub><sup>*</sup>

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The wavelength-modulated transmission spectra near the fundamental absorption edges of ZrS2 and HfS2 have been studied. The observed spectra are well described by the theory of the indirect transitions with excitonic effect. The structures in the spectra are assigned to the indirect transitions, Γ2L1+ and Γ2M1+. From the fitting of the observed spectra to the theoretical curves, the parameters including the band gap energies, the binding energies of the excitons, and the phonon energies at L and M points of ZrS2 and HfS2, are determined.

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