Hydrogen and PO4 Modes of RbH2PO4

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  • Hydrogen and PO<SUB>4</SUB> Modes of RbH<SUB>2</SUB>PO<SUB>4</SUB>

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Hydrogen and PO4 modes in RbH2PO4 (RDP) have been investigated by inelastic neutron scattering and Raman scattering experiments. Two large peaks at 124 meV and 159 meV in neutron scattering spectra are confirmed to hydrogen modes by comparing with Raman scattering spectra. These peak widths change around the ferroelectric phase transition temperature. This is considered to be due to the order or disorder of the PO4 tetrahedrons which affect the motion of hydrogen atoms.

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