X-Ray Emission Spectra and Electronic Structures of Red Phosphorus, 3d Transition-Metal Phosphides and III-V Compounds.

DOI Web Site Web Site BIBCODE 2 Citations 161 References
  • Sugiura Chikara
    Department of Electrical and Electronic Engineering, Faculty of Engineering, Utsunomiya University, Utsunomiya 321

Bibliographic Information

Other Title
  • X-Ray Emission Spectra and Electronic Structures of Red Phosphorus,3d Transition-Metal Phosphides and 3-5 Compounds
  • X Ray Emission Spectra and Electronic S
  • X-Ray Emission Spectra and Electronic Structures of Red Phosphorus, 3<i>d</i>Transition-Metal Phosphides and III–V Compounds

Search this article

Description

The P Kβ emission spectra in fluorescence from red amorphous phosphorus, 3d transition-metal phosphides TiP, CrP, FeP, Fe2P, Fe3P, CoP, Co2P, Ni5P4, Ni2P, Ni3P, Cu3P, ZnP2 (black) and Zn3P2, and the semiconducting phosphides of the III-V type, BP, AlP, GaP and InP are measured with a high-resolution two-crystal vacuum spectrometer equipped with Ge(111) crystals. The influence of the metal atoms appears distinctly on the P Kβ fluorescence emission spectra. The measured spectra are compared with available X-ray emission and XPS valence-band spectra and theoretical energy-band calculations on a common energy scale. It is shown that considerable p-d, s mixing occurs in the valence bands of the 3d transition-metal phosphides and the P 3p states mix fairly with the P 3s states in the valence bands of red phosphorus, Gap and InP

Journal

Citations (2)*help

See more

References(161)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top