Low Dimensionality Observed by ESR Measurements in<i>S</i>=1 Spin Ladder Substance BIP-TENO (3,3<sup>′</sup>,5,5<sup>′</sup>-tetrakis(<i>N</i>-tert-butylaminoxyl)biphenyl)

  • Ohta Hitoshi
    Molecular Photoscience Research Center, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 Venture Business Laboratory, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501
  • Kirita Keizo
    Venture Business Laboratory, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 Graduate School of Science and Technology, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501
  • Kunimoto Takashi
    Venture Business Laboratory, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501
  • Okubo Susumu
    Molecular Photoscience Research Center, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 Venture Business Laboratory, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501
  • Hosokoshi Yuko
    Institute for Molecular Science and Grad. Univ. Advanced Studies, Okazaki 444-8585
  • Katoh Keiichi
    Institute for Molecular Science and Grad. Univ. Advanced Studies, Okazaki 444-8585
  • Inoue Katsuya
    Institute for Molecular Science and Grad. Univ. Advanced Studies, Okazaki 444-8585
  • Ogasahara Akira
    Department of Applied Physics, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656
  • Miyashita Seiji
    Department of Applied Physics, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656

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タイトル別名
  • Low Dimensionality Observed by ESR Measurements in S=1 Spin Ladder Substance BIP-TENO (3,3',5,5'-tetrakis(N-tert-butylaminoxyl)biphenyl).

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説明

X-band ESR measurements of BIP-TENO (3,3,5,5-tetrakis(N-tert-butylaminoxyl)biphenyl) single crystal, which is an S=1 spin ladder model substance, have been performed in the temperature region from 3.5 to 300 K. At room temperature, the angular dependences of g-value and line width were observed. The line shape and the angular dependence of the line width showed typical behavior of a low-dimensional antiferromagnet. The temperature dependence measurements showed the minimum of the line width and the dynamical g-shift, which were also typical behaviors of a low-dimensional antiferromagnet. However, the direction of the dynamical g-shift does not coincide with Nagata's well-known theory, and the comparison with the recent direct ESR calculation by Miyashita et al. [S. Miyashita, T. Yoshino and A. Ogasahara: J. Phys. Soc. Jpn. 68 (1999) 655] is discussed.

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