Effect of Hydrostatic Pressure on the Phase Transitions in K2ZnCl4

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  • Effect of Hydrostatic Pressure on the Phase Transitions in K<SUB>2</SUB>ZnCl<SUB>4</SUB>
  • Effect of Hydrostatic Pressure on the P

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Effect of hydrostatic pressure on the normal(I)-incommensurate(II)-ferroelectric(III) phase transitions in K2ZnCl4 was studied by differential thermal analysis and dielectric constant measurements. The I–II transition temperature (283°C at 0 GPa) increases with increasing pressure with a rate of 110 K GPa−1. The II–III transition temperature (the ferroelectric Curie temperature: 127°C at 0 GPa) decreases with an initial slope of −86.2 K GPa−1 as pressure increases. The results were compared with previously reported pressure effects of other K2SeO4-group ferroelectrics.

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