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Stacking Ordering in K-Graphite Intercalation Compounds (Stager 1–8)
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- Nishitani Ryusuke
- Research Institute for Iron, Steel and Other Metals, Tohoku University
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- Suda Kei
- Institute of Materials Science, University of Tsukuba
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- Suematsu Hiroyoshi
- Institute of Materials Science, University of Tsukuba
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Description
The stacking order of graphite and K-layers in K-graphite intercalation compounds (GIC) has been studied by in situ X-ray diffraction measurements. The stacking sequence of graphite layers for stage n=2−8 is described as |(AB)n⁄2|(BC)n⁄2|(CA)n⁄2| for even-numbered stage, and |A(BA)(n−1)⁄2|A(CA)(n−1)⁄2| for odd-numbered stage, where the vertical line denotes a K-layer, and A, B and C the stackings of graphite layers. The long range ordering of the stacking sequence can be interpreted by a stacking change model for stage transition. Stacking faults, which are remarkable in stage 2, can be understood as a consequence of stage transition in the proposed model. Two solid phases of different K-layer stackings, αβ and αβγδ, have been observed in stage 1 at elevated temperatures.
Journal
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 55 (5), 1601-1612, 1986
THE PHYSICAL SOCIETY OF JAPAN
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Keywords
Details 詳細情報について
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- CRID
- 1390282679162357504
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- NII Article ID
- 210000092682
- 130003739676
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- BIBCODE
- 1986JPSJ...55.1601N
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- COI
- 1:CAS:528:DyaL28XkvV2qtLk%3D
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- ISSN
- 13474073
- 00319015
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed