Intermediate Valence State of La0.9Eu0.1Ni2(Si1-xGex)2 Compounds

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  • Intermediate Valence State of La<sub>0.9</sub>Eu<sub>0.1</sub>Ni<sub>2</sub>(Si<sub>1-<i>x</i></sub>Ge<sub><i>x</i></sub>)<sub>2</sub>Compounds

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We examined the temperature dependence of the Eu valence in La0.9Eu0.1Ni2(Si1−xGex)2 by means of magnetic susceptibility measurements and X-ray absorption spectroscopy. It was found that the Eu ions are in the intermediate valence state for 0.2≤x≤0.8 and the Eu valence gradually varies with temperature. The results are compared with those of the concentrated EuNi2(Si1−yGey)2 compounds. The main factor in determining the Eu valence in both dilute and concentrated alloys is discussed.

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