Direct Observation of"Soliton-Like"Spin Density Distribution in Undoped Cis-Rich(CH)x Using ENDOR

書誌事項

タイトル別名
  • Direct Observation of ‘Soliton-Like’ Spin Density Distribution in Undoped <I>Cis</I>-Rich (CH)<I><SUB>x</SUB></I> Using ENDOR
  • Direct Observation of Soliton Like Spin
  • Direct Observation of `Soliton-Like' Spin Density Distribution in Undoped<i>Cis</i>-Rich (CH)<sub><i>x</i></sub>Using ENDOR
公開日
1985
DOI
  • 10.1143/jpsj.54.3956
公開者
一般社団法人 日本物理学会

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説明

Electron nuclear double resonance (ENDOR) measurements were performed on stretch oriented undoped cis-rich (CH)x at 4 K. The observed ENDOR line shape had spectral turning points and showed a clear anisotropy. The presence of the spin density which is comparable with the prediction of the soliton theory was directly confirmed from the maximum ENDOR frequency. The analysis of the observed line shape using a spectrum simulation method suggested that the spin density is of the form similar as those predicted by the soliton theory for finite on-site Coulomb energy. Especially the spectral turning points observed when the external magnetic field was parallel to the stretch direction of the sample were directly correlated to the existence of the negative spin density predicted by the theory.

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