Role of <i>p</i>– <i>f</i> Hybridization in the Metal–Nonmetal Transition of PrRu<sub>4</sub>P<sub>12</sub>
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- Iwasa Kazuaki
- Department of Physics, Tohoku University
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- Hao Lijie
- Department of Physics, Tohoku University
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- Hasegawa Tomoo
- Department of Physics, Tohoku University
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- Takagi Toshiaki
- Department of Physics, Tohoku University
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- Horiuchi Kenji
- Department of Physics, Tohoku University
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- Mori Yoshiaki
- Department of Physics, Tohoku University
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- Murakami Youichi
- Department of Physics, Tohoku University
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- Kuwahara Keitaro
- Department of Physics, Tokyo Metropolitan University
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- Kohgi Masahumi
- Department of Physics, Tokyo Metropolitan University
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- Sugawara Hitoshi
- Department of Mathematical and Natural Sciences, The University of Tokushima
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- Saha Shanta Ranjan
- Muon Science Laboratory, Institute of Material Structure Science, High Energy Accelerator Research Organization
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- Aoki Yuji
- Department of Physics, Tokyo Metropolitan University
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- Sato Hideyuki
- Department of Physics, Tokyo Metropolitan University
書誌事項
- タイトル別名
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- Role of p- f Hybridization in the Metal-Nonmetal Transition of PrRu4P12
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説明
Electronic state evolution in the metal–nonmetal transition of PrRu4P12 has been studied by X-ray and polarized neutron diffraction experiments. It has been revealed that, in the low-temperature nonmetallic phase, two inequivalent crystal-field (CF) schemes of Pr3+ 4f2 electrons with Γ1 and Γ4(2) ground states are located at Pr1 and Pr2 sites forming the bcc unit cell surrounded by the smaller and larger cubic Ru-ion sublattices, respectively. This modulated electronic state can be explained by the p–f hybridization mechanism taking two intermediate states of 4f1 and 4f3. The p–f hybridization effect plays an important role in the electronic energy gain in the metal–nonmetal transition originated from the Fermi surface nesting.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 74 (7), 1930-1933, 2005
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390282679164719744
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- NII論文ID
- 210000105530
- 110001979643
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- NII書誌ID
- AA00704814
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- BIBCODE
- 2005JPSJ...74.1930I
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 7356903
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDLサーチ
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