Br<SUB>2</SUB><SUP>−</SUP> Molecular Ions in Simple Cubic CsBr

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  • Ueda Yoshifumi
    Department of Physics, Faculty of Science, Hiroshima University
  • Fujita Toshiaki
    Department of Applied Physics, Faculty of Engineering, Hiroshima University
  • Kazumata Yukio
    Japan Atomic Energy Research Institute
  • Nishi Masato
    Department of Applied Physics, Faculty of Engineering, Hiroshima University

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  • Br2- Molecular Ions in Simple Cubic CsBr
  • Br<sub>2</sub><sup>-</sup> Molecular Ions in Simple Cubic CsBr

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Abstract

Br2− molecular ions in simple cubic CsBr produced with 60Co γ-rays at liquid nitrogen temperature have been studied by EPR. EPR spectra have been analyzed in terms of the usual spin-Hamiltonian on the assumption of axial symmetry of the molecular ions. The parameters are determined to be g⁄⁄=1.9824, g⊥=2.171, A⁄⁄=432.8 G and A⊥=73.0 G for the 81Br2− molecular ion by using the value of 28.5 G for the nuclear quadrupole term. These molecular ions decayed thermally above 165 K.

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