EPR Studies of Gd3+,Dy3+,and Ce3+ in Some Van Vleck Paramagnets

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  • EPR Studies of Gd<SUP>3+</SUP>, Dy<SUP>3+</SUP>, and Ce<SUP>3+</SUP> in some Van Vleck Paramagnets
  • EPR Studies of Gd3 + Dy3 + and Ce3 + in

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説明

EPR of Gd3+ in the Van Vleck paramagnets, PrPb3 and TmCd have been investigated. The temperature-dependent linewidths have been found to be in agreement with the prediction of Moriya and Obata. In a complementary study, non-S-State Dy3+ in TmP, TmAs, PrP, PrAs, PrSb, PrBi and PrS, and Ce3+ in TmS, TmAs, PrS and PrP have been examined. For all these cases, (S-state as well as the non-S-state magnetic ions), the temperature variation of the g-shifts follows the susceptibilities of the hosts. The exchange coupling constants between the impurity ions and the host magnetic ions have been obtained.

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