Crystal Field Splittings in Fe<SUP>2+</SUP> Tutton Salts from Mössbauer Studies
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- Raj Deo
- Department of Physics, University of Roorkee
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- Chandra K.
- Department of Physics, University of Roorkee
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- Puri S. P.
- Department of Physics, University of Roorkee
Bibliographic Information
- Other Title
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- Crystal field splittings in Fe2+ tutton salts from Mossbauer studies
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Abstract
The Mössbauer spectra of Fe2+ Tutton salts, which form an isomorphous series of hydrated double sulphates having the general formula Fe(MSO4)2·6H2O, M=NH4+, K+, Rb+ and Cs+ have been studied over a temperature range from 77°–300°K. The data is analysed to assign characteristic temperatures of the t2g levels and find their splittings. It is concluded that the ground state wave function is singlet |xy> in all these cases. Furthermore the effect of varying electronegativity of M has negligible effect on isomer shift.
Journal
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 24 (1), 35-38, 1968
THE PHYSICAL SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390282679170274944
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- NII Article ID
- 40018663463
- 210000080352
- 130003891837
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- NII Book ID
- AA00704814
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- BIBCODE
- 1968JPSJ...24...35R
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- COI
- 1:CAS:528:DyaF1cXptFOgsA%3D%3D
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- ISSN
- 13474073
- 00319015
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- NDL BIB ID
- 8501494
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed