Electron paramagnetic resonance study of Ag++ ions in CdCl2

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  • Electron Paramagnetic Resonance Study of Ag<SUP>++</SUP> Ions in CdCl<SUB>2</SUB>

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The EPR spectra of a Ag++ ion in CdCl2 are studied at liquid nitrogen temperature and at room temperature. The Ag++ ion is found at the center of the octahedron of six Cl ions. The octahedron of Cl ions is elongated tetragonally due to a Jahn-Teller effect at liquid nitrogen temperature. It is also observed that the principal axis of the g-tensor deviates from a line joining the Ag++ ion and one of the nearest neighbor Cl ions towards the crystal c-axis. This deviation is interpreted to be due to the influence of the axial symmetry field parallel to the c-axis on the Jahn-Teller effect. At room temperature a single broad EPR line with axial symmetry is observed.

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