Polarized Neutron Diffraction Study of a CuCr<SUB>2</SUB>Se<SUB>4</SUB> Single Crystal
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- Yamashita Osamu
- The Research Institute for Iron, Steel and Other Metals, Tohoku University
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- Yamaguchi Yasuo
- The Research Institute for Iron, Steel and Other Metals, Tohoku University
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- Nakatani Isao
- National Research Institute for Metals
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- Watanabe Hiroshi
- The Research Institute for Iron, Steel and Other Metals, Tohoku University
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- Masumoto Katashi
- National Research Institute for Metals
Bibliographic Information
- Other Title
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- Polarized Neutron Diffraction Study of a CuCr2Se4 Single Crystal
- Polarized Neutron Diffraction Study of
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Abstract
The electronic state of CuCr2Se4 is investigated by means of the polarized neutron diffraction technique. From the measured form factors of copper and chromium atoms, the magnetic moments are determined to be −0.07±0.02 (μB/Cu) and 2.64±0.04 (μB/Cr), respectively. Further, the uniform polarization existent throughout the crystal is estimated to be −0.20±0.11 μB per formula unit, using the total moment 5.01±0.01 (μB/CuCr2Se4) obtained from the magnetization measurement. This result which differs from those reported by other authors with neutron diffraction, shows that neither of the ionic configuration models of Cu+[Cr3+Cr4+]Se4 and Cu2+[Cr23+]Se4 gives a satisfactory explanation of CuCr2Se4, although the former is closer to the experimental data. The form factor of the chromium atom agrees well with the calculated free ion form factor for Cr+, but not for Cr3+, and this fact indicates that the unpaired electron density on the chromium atom is more spread than that for free Cr3+. It is found that 84±16% of the unpaired 3d electrons occupy t2g orbitals.
Journal
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 46 (4), 1145-1152, 1979
THE PHYSICAL SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390282679172245504
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- NII Article ID
- 210000087732
- 110001975506
- 130003737799
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- NII Book ID
- AA00704814
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- BIBCODE
- 1979JPSJ...46.1145Y
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- COI
- 1:CAS:528:DyaE1MXitFSgs7Y%3D
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- ISSN
- 13474073
- 00319015
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- NDL BIB ID
- 2048145
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed