Mechanism of Chirality Conversion by Grinding Crystals: Ostwald Ripening vs Crystallization of Chiral Clusters
-
- Uwaha Makio
- Department of Physics, Nagoya University
-
- Katsuno Hiroyasu
- Department of Physics, Nagoya University
この論文をさがす
抄録
It has been found that the simple grinding of crystals in a solution causes the conversion of the chiral structure of crystals and, in the case of organic molecules, the resultant conversion of molecular chirality. In order to clarify the mechanism of the chirality conversion, we study the change in the size distribution of chiral clusters in a Becker–Döring type model, in which chiral dimer reaction and grinding are implemented. In the absence of grinding, Ostwald ripening may cause chirality conversion if the initial size distribution is appropriate. With grinding crystals, the crystallization of chiral clusters causes an exponential amplification of the initial chiral imbalance resulting in a homochiral state. During chirality conversion, the total size distribution does not change.
収録刊行物
-
- Journal of the Physical Society of Japan
-
Journal of the Physical Society of Japan 78 (2), 023601-023601, 2009
一般社団法人 日本物理学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282679173482112
-
- NII論文ID
- 110007097899
- 130005437338
- 210000107646
-
- NII書誌ID
- AA00704814
-
- ISSN
- 13474073
- 00319015
-
- HANDLE
- 2237/13866
-
- NDL書誌ID
- 9799893
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- IRDB
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- 抄録ライセンスフラグ
- 使用不可