The synthesis and characterization of double-layered perovskite Sr3Mo2O7

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  • The Synthesis and Characterization of Double-Layered Perovskite Sr<SUB>3</SUB>Mo<SUB>2</SUB>O<SUB>7</SUB>

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Sr3Mo2O7 is a member of the Ruddlesden–Popper type series of Srn+1MonO3n+1 with n=2, a so-called double layered perovskite. We have successfully synthesized polycrystalline samples of single-phase Sr3Mo2O7 with the aid of Ti2O3 as p(O2) buffer. The phase-pure samples allowed us to perform measurements of the electrical resistivity and the magnetic susceptibility on Sr3Mo2O7 for the first time. The resistivity revealed that Sr3Mo2O7 is a metallic conductor from 300 K to 30 mK. The Pauli-paramagnetic behavior is observed in the susceptibility. This means that Srn+1MonO3n+1 for n=1, 2, and ∞ all show the Pauli-paramagnetic metal behavior, in contrast to Srn+1RunO3n+1 of an electronic analogue series.

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