Conversion in Visible Light-cured Resins III : Kinds of Monomers and Photoinitiator Compositions

DOI 7 Citations
  • HIROSE Hideharu
    Department of Dental Materials, Nihon University School of Dentistry
  • KIKUCHI Hisaji
    Department of Dental Materials, Nihon University School of Dentistry
  • MIYAZAKI Kiyomi
    Department of Dental Materials, Nihon University School of Dentistry
  • TOMOKIYO Naoshi
    Department of Dental Materials, Nihon University School of Dentistry
  • TAKANO Mamoru
    Department of Dental Materials, Nihon University School of Dentistry
  • YOSHIHASHI Kazue
    Department of Dental Materials, Nihon University School of Dentistry
  • ANZAI Misaki
    Department of Dental Materials, Nihon University School of Dentistry
  • NISHIYAMA Minoru
    Department of Dental Materials, Nihon University School of Dentistry

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  • 可視光線重合型レジンの重合率に関する基礎的研究III : モノマーの種類および触媒組成と重合率との関係

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Abstract

The quantity of the remaining double bonds (RDB) in sixty-six kinds of polymerized visible ligth-cured resins was measured. As monomers, three kinds of cyclophosphazene monomers and eigth kinds of commercial monomers were prepared for the visible ligth-cured resins by changing the photoinitiator compositions (six kinds). Trial resins were investigated by means of a FT-IR with the liquid film method. The infrared absorbance measurements were made before irradiation and chronologically repeated after the resins had been polymerized by irradiation for 90sec. The quantity of RDB of all trial resins decreased linearly with the logarithmic time after the start of irradiation. When the inhibitor (BHT) was added, the order of the conversion was: 9G>BPE-200≧4G≧3G≧U-2TH>BPE-100>(EMP-800+3G)≧2.6E>(EMA)6 > (EMA))7)>(EMA))8). When the inhibitor was not added, the order of the conversion was: BPE-200>9G≧4G≧3G≧U-2TH>BPE-100>(EPM-800+3G)≧2.6E>(EMA))6)>(EMA))7)>(EMA))8). The conversion increased with the decrease in the number of polymerization group in cyclophosphazene resins and with the increase of the CH)2)CH)2)O chain length in EDMA and BMPEPP resins. The resins with photoinitiator composition A (CQ 0.50wt%, DMAEM 1.00wt% and BHT 0.01wt%) and C (CQ 0.30wt%, DB 0.15wt%, DMAB-EMA 1.40wt% and BHT 0.01wt%) were preferable, showing high conversion. The resins not containing the inhibitor showed higher conversion than those containing the inhibitor, but had a shorter shelf life.

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