多種類の米中の総ヒ素定量法および無機ヒ素を分別定量するための硝酸部分分解法の検討

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  • Determination Method for Total Arsenic and Partial-digestion Method with Nitric Acid for Inorganic Arsenic Speciation in Several Varieties of Rice

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説明

The determination method of total arsenic (As) and the speciation method of inorganic As for non-glutinous rice reported in our preceding paper were applied to several varieties of rice under optimized experimental conditions. In the determination of total As with ICP-MS, acetic acid was added to increase the sensitivity and an internal reference method with germanium was adopted to increase the precision. The extraction temperature in the partial-digestion method with nitric acid to speciate inorganic As was raised to 100°C, because extraction efficiency over 90% was obtained from glutinous rice and colored rice at this temperature. In the investigation of polished and unpolished forms of non-glutinous, glutinous, and colored rice, the amounts of total and inorganic As were 0.04-0.54 mg/kg and 0.02-0.41 mg/kg, respectively. The color of rice was not related to total or inorganic As content. These results indicate that the inorganic As content in commercial rice should be carefully monitored.

収録刊行物

  • 食品衛生学雑誌

    食品衛生学雑誌 51 (4), 178-181, 2010

    公益社団法人 日本食品衛生学会

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