書誌事項
- タイトル別名
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- Finely designed arrangements and photoelectronic properties of supramolecular nanocarbons composed of fullerenes and cyclic porphyrin dimers
- フラーレン ト ポルフィリン カラ ナル チョウブンシケイ ナノカーボン ノ ハイレツ セイギョ ト ヒカリ ・ デンシ ブッセイ
この論文をさがす
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We have studied the supramolecular structures and photoelectronic properties of inclusion complexes of cyclic porphyrin dimers (M2-CPDPy, M=Ni, 2H) and fullerenes (C60, C70, PCBM ([6,6]-phenyl-C61-butyric acid methyl ester) and Li+@C60). The porphyrin dimers have self-assembling 4-pyridyl groups at the meso positions and include fullerenes in their cavities with high affinities (Kassoc≈105 M-1). In crystals, C60⊂Ni2-CPDPy and PCBM⊂Ni2-CPDPy give self-assembled porphyrin nanotubes containing the linear arrays of fullerene molecules. These self-assemblies are induced mainly by the non-classical hydrogen bonds between pyridyl nitrogens and porphyin β C-H groups. On the other hand, in the crystals of C60⊂H4-CPDPy and C70⊂H4-CPDPy, the included fullerene molecules show zigzag chains through van der Waals contacts with each other. Due to these well-ordered arrays of C60, both crystals of C60⊂Ni2-CPDPy and C60⊂H4-CPDPy have high charge mobilities (Σμ>0.1 cm2 V-1 s-1). C60⊂H4-CPDPy shows photoinduced electron transfer from the porphyrin moieties to C60 and photovoltaic activity with IPCEmax=17% in photoelectrochemical cells. Moreover, the inclusion complexes of lithium-ion-encapsulated C60(Li+@C60) and M2-CPDPy exhibit photoinduced charge separation with very long lifetimes reaching submillisecond order.
収録刊行物
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- 炭素
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炭素 2013 (260), 284-291, 2013
炭素材料学会
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詳細情報 詳細情報について
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- CRID
- 1390282679207248896
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- NII論文ID
- 130003386040
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- NII書誌ID
- AN00140335
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- ISSN
- 18845495
- 03715345
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- NDL書誌ID
- 025022385
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可