Reflection Electron Microscopy of Copper Electrocrystallization on Platinum
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- Jyoko Yukimi
- Faculty of Engineering, Kyushu University
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- Koyama Ryuji
- Faculty of Engineering, Kyushu University
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- Hayashi Yasunori
- Faculty of Engineering, Kyushu University
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説明
Monatomic steps on Pt single crystal surfaces have been directly imaged in a conventional electron microscope in reflection mode. With the reflection electron microscopy (REM) technique the surface topography of Pt single crystal spheres at the progressive stages of Cu electrocrystallization has been studied. Although the formation of Cu submonolayer superstructures on Pt(111) surfaces has not yet been detected, a layered Cu deposition of one monolayer or two and the Stranski-Krastanov type crystal growth, which is influenced by the surface steps, have been observed. Deposition of bulk Cu and subsequent stripping altered the Pt(111) surface, leaving traces of the Cu deposit geometry on the bare Pt surface after removal of Cu by anodic stripping. No such a surface change was visible during Cu adsorption-desorption cycles only in the underpotential region. The observed REM images have been discussed in terms of surface rearrangements during Cu electrocrystallization due to the formation of layered deposition and bulky island crystals.
収録刊行物
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- Materials Transactions, JIM
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Materials Transactions, JIM 32 (6), 546-550, 1991
社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282679225343488
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- NII論文ID
- 130003555969
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- COI
- 1:CAS:528:DyaK3MXmtFOht7k%3D
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- ISSN
- 2432471X
- 09161821
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 使用不可