Changes in Hydrogen Permeability and Microstructures of Nb-(Ti, Zr)Ni Alloys by Cold Rolling and Annealing
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- Tang Huxiang
- Department of Materials Science, Kitami Institute of Technology
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- Ishikawa Kazuhiro
- Department of Materials Science, Kitami Institute of Technology
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- Aoki Kiyoshi
- Department of Materials Science, Kitami Institute of Technology
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Maximum cold rolling reduction rates of as-cast Nb40Ti30−xZrxNi30 alloys were measured to evaluate ductility by measuring the change in the thickness. 50% or higher reduction rates were obtained for the alloys containing the Zr content of 12 mol% or less, but lower values were obtained for the alloys substituted with more Zr. Changes of hydrogen permeability (Φ) and microstructures of the Nb40Ti18Zr12Ni30 alloy caused by cold-rolling and subsequent vacuum annealing were investigated. Φ of this alloy was reduced to the half of the as-cast one by the 50% reduction rate, but recovered to 3.23×10−8 [molH2m−1 s−1 Pa−0.5], which is 1.13 times higher than that of as-cast one, by a subsequent annealing for 360 ks at 1273 K. Although the eutectic phase disappeared and was replaced by a small spherical (Nb, Ti, Zr) phase embedded in the (Ti, Zr)Ni matrix after rolling and subsequent annealing, these alloys showed good resistance to the hydrogen embrittlement at 523 K or more.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 48 (9), 2454-2458, 2007
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282679226286464
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- NII論文ID
- 10019853845
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 8885358
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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