Polymeric Co-C<SUB>60</SUB> Compound Phase Evolved in Atomistically Mixed Thin Films

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  • Sakai Seiji
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Naramoto Hiroshi
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Lavrentiev Vasily
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Narumi Kazumasa
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Maekawa Masaki
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Kawasuso Atsuo
    Takasaki-branch, Advanced Science Research Center, Japan Atomic Energy Research Institute
  • Yaita Tsuyoshi
    Department of Materials Science, Japan Atomic Energy Research Institute
  • Baba Yuji
    Synchrotron Radiation Center, Japan Atomic Energy Research Institute

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  • Polymeric Co-C60 Compound Phase Evolved in Atomistically Mixed Thin Films

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Abstract

A systematic study of the atom-level mixtures between Co and C60 has made possible to find a new C60-based compound phase, CoxC60 (x≤5). It is confirmed with the EXAFS analysis and the positron annihilation study that the polymeric structure is developed three-dimensionally by bridging two C60 molecules with the covalently bonded Co atom.

Journal

  • MATERIALS TRANSACTIONS

    MATERIALS TRANSACTIONS 46 (4), 765-768, 2005

    The Japan Institute of Metals and Materials

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