Local structure around Pd atoms in Pd42.5Ni7.5Cu30P20 excellent glass-former studied by anomalous X-ray scattering
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- Hosokawa Shinya
- Institut für Physikalische-, Kern-, und Makromolekulare Chemie, Philipps Universität Marburg Center for Materials Research using Third-Generation Synchrotron Radiation Facilities, Hiroshima Institute of Technology
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- Bérar Jean-François
- Institut Néel, CNRS
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- Boudet Nathalie
- Institut Néel, CNRS
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- Ichitsubo Tetsu
- Department of Materials Science and Engineering, Graduate School of Engineering, Kyoto University
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- Matsubara Eiichiro
- Department of Materials Science and Engineering, Graduate School of Engineering, Kyoto University
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- Nishiyama Nobuyuki
- R&D Institute of Metals and Composites for Future Industries (RIMCOF)
書誌事項
- タイトル別名
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- Local Structure around Pd Atoms in Pd<SUB>42.5</SUB>Ni<SUB>7.5</SUB>Cu<SUB>30</SUB>P<SUB>20</SUB> Excellent Glass-Former Studied by Anomalous X-ray Scattering
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In order to study local structure around the Pd atoms in Pd42.5Ni7.5Cu30P20 excellent metallic glass-former, an anomalous X-ray scattering (AXS) experiment was performed at energies close to the Pd K absorption edge at the beamline BM02 of the European Synchrotron Radiation Facility. The differential structure factor, ΔPdS(Q), was obtained with a good statistical quality, which demonstrates that a pre-shoulder at about 20 nm−1, indicating the existence of an intermediate-range order, originates from the Pd-Pd atomic correlation. The first peak in the differential pair correlation function, ΔPdg(r), shows a longer inter-atomic length around the Pd atoms than the average value. The local structure around the Pd atoms is discussed in detail by comparing to the previous experiments of AXS and electronic structure.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 48 (9), 2358-2361, 2007
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282679226753152
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- NII論文ID
- 10019853427
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 8884899
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可