Thermal Cycle Resistance of Yttria Stabilized Zirconia Coatings Prepared by MO-CVD

  • Tu Rong
    Institute for Materials Research, Tohoku University
  • Goto Takashi
    Institute for Materials Research, Tohoku University

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Yttria stabilized zirconia (YSZ) coatings containing 0 to 9.5 mol% Y2O3 were prepared on Hastelloy-XR alloys by metal-organic chemical vapor deposition (MO-CVD), and the effect of Y2O3 content on thermal cycle resistance was investigated in the temperature intervals from 600 to 1273 K and from 600 to 1373 K in air. In the 600–1273 K interval, delamination after 1200 cycles had not occurred for any of the Y2O3 contents of YSZ coatings. In the 600–1373 K interval, the YSZ coatings containing 0, 0.5 and 9.5 mol% Y2O3 suffered partial delamination after 1200 cycles, while no delamination was observed for the YSZ coatings containing 4 mol% Y2O3. During the thermal cycles, thermally grown oxide (TGO) layers consisting of inner Cr2O3 and outer (Ni,Mn,Fe)(Fe,Cr)2O4 spinel were formed at the YSZ coating/Hastelloy-XR substrate alloy interface. The delamination of YSZ coatings occurred at the alloy side near the TGO layer/Hastelloy-XR alloy interface.

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