Electrochemical Coating with Poly(phenylene oxide) Films Bearing Oligoether Groups as a Tool for Elimination of Protein Adsorption to Electrode Surfaces.
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- MAEDA Hatsuo
- Graduate School of Pharmaceutical Sciences, Osaka University
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- OKADA Tamaki
- Graduate School of Pharmaceutical Sciences, Osaka University
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- MATSUMOTO Yoriko
- Graduate School of Pharmaceutical Sciences, Osaka University
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- KATAYAMA Kazunori
- Graduate School of Pharmaceutical Sciences, Osaka University
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- YAMAUCHI Yuji
- Graduate School of Pharmaceutical Sciences, Osaka University
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- OHMORI Hidenobu
- Graduate School of Pharmaceutical Sciences, Osaka University
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Reported herein are the adsorption properties of bovine serum albumin to glassy carbon (GC) electrodes coated with poly(phenylene oxide) (PPO) films formed by anodic polymerization of HOC6H4R in phosphate buffer (pH 7.4), where R=o-, m-, and p-MeO- or m-Me(OCH2CH2)nO- (n=1 - 4) group. Evaluation of the voltammetric response of caffeic acid demonstrated that a GC electrode coated with a PPO film derived from m-HOC6H4O(CH2CH2O)4Me not only shows satisfactory electrochemical performance but also resists surface fouling due to protein adsorption. Coating with the film also proved to be useful in preventing the surface of a gold electrode from being fouled by protein adsorption.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 15 (7), 633-639, 1999
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679229101568
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- NII論文ID
- 130004440092
- 10004706667
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- NII書誌ID
- AA10500785
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- COI
- 1:CAS:528:DyaK1MXks1WqsL4%3D
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 4784179
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可