Supporting electrolytes for voltammetric study of ion transfer at nitrobenzene/water interface.

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  • OSAKAI Toshiyuki
    Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University
  • KAKUTANI Tadaaki
    Research Center for Cell and Tissue Culture, Faculty of Agriculture, Kyoto University
  • NISHIWAKI Yoshinori
    Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University
  • SENDA Mitsugi
    Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University

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Description

The polarizable potential range was determined by cyclic voltammetry for the interface between an aqueous solution of lithium chloride or magnesium sulfate and a nitrobenzene solution of various electrolytes: tetrabutylammonium salts of tetraphenylborate, tetrakis(4-fluorophenyl)borate, tetrakis(4-chlorophenyl)borate, and tetrakis[3, 5- bis(trifluoromethyl)phenyl]borate, and tetrapentyl- and tetrahexylammonium salts of tetraphenylborate. The anodic and cathodic limits of polarizable potential range were discussed with reference to the standard ion-transfer potentials of the supporting-electrolyte ions.

Journal

  • Analytical Sciences

    Analytical Sciences 3 (6), 499-503, 1987

    The Japan Society for Analytical Chemistry

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