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Infrared Spectroscopic Analyses of Transformations of Chemical Species on the Silica Highly-Reacted with Gaseous BF3.
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- YOSHIDOME Toshifumi
- Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University
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- DANG Zhongyuan
- Department of Chemistry, University of Ottawa
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- MORROW Barry A.
- Department of Chemistry, University of Ottawa
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Description
Transformations of chemical species formed by the reaction of gaseous BF3 with high pressure and silica preheated at 473 and 1093 K were studied with the use of infrared absorption spectrometry. The species containing -BF2 and the species containing>BF were transformed to each other on the highly-reacted silica depending on the pressure of BF3 in cell, and some of the species containing -BF2 were also desorbed without their transformations to the species containing>BF. H2O played important roles in these transformations.
Journal
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- Analytical Sciences
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Analytical Sciences 19 (3), 429-435, 2003
The Japan Society for Analytical Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390282679232421120
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- NII Article ID
- 130004440742
- 80015831095
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- NII Book ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL BIB ID
- 6476118
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- PubMed
- 12675354
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- JaLC
- NDL Search
- Crossref
- PubMed
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed