Infrared Spectroscopic Analyses of Transformations of Chemical Species on the Silica Highly-Reacted with Gaseous BF3.

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Transformations of chemical species formed by the reaction of gaseous BF3 with high pressure and silica preheated at 473 and 1093 K were studied with the use of infrared absorption spectrometry. The species containing -BF2 and the species containing>BF were transformed to each other on the highly-reacted silica depending on the pressure of BF3 in cell, and some of the species containing -BF2 were also desorbed without their transformations to the species containing>BF. H2O played important roles in these transformations.

Journal

  • Analytical Sciences

    Analytical Sciences 19 (3), 429-435, 2003

    The Japan Society for Analytical Chemistry

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