Highly Potent Chiral Labeling Reagents for the Discrimination of Chiral Alcohols*

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Abstract

Highly sensitive chiral labeling reagents, (1R,2R)- and (1S,2S)-2-(2,3-anthracenedicarboximido)cyclohexanecarboxylic acids [(1R,2R)- and (1S,2S)-A] and (1R,2R)- and (1S,2S)-2-(2,3-naphthalenedicarboximido)cyclohexanecarboxylic acids [(1R,2R)- and (1S,2S)-A′], were prepared. Reagent A has enabled us to discriminate the enantiomers of anteiso fatty alcohols up to C9 methyl branching by 1H NMR, and both reagents A and A′ have allowed up to C16 methyl branching at the 10-15 molar level by fluorescence detected reversed-phase HPLC.

Journal

  • Analytical Sciences

    Analytical Sciences 19 (9), 1243-1249, 2003

    The Japan Society for Analytical Chemistry

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