Voltammetric Response of Phenylboronic Acid Monolayer-modified Gold Electrode to Sugars
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- TAKAHASHI Shigehiro
- Graduate School of Pharmaceutical Sciences, Tohoku University
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- KASHIWAGI Yoshitomo
- Graduate School of Pharmaceutical Sciences, Tohoku University
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- HOSHI Tomonori
- Graduate School of Pharmaceutical Sciences, Tohoku University
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- ANZAI Jun-ichi
- Graduate School of Pharmaceutical Sciences, Tohoku University
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Abstract
The surface of a gold (Au) disk electrode was modified with a self-assembled monolayer consisting of phenylboronic acid moiety to fabricate a voltammetric sensor sensitive to sugars. The modified Au electrode exhibited a voltammetric response to sugars in the presence of Fe(CN)63- ion in the sample solution at neutral pH. The peak current of the cyclic voltammograms decreased depending on the type and concentration of sugars. The dynamic range of the electrode is 3 - 100 mM for glucose and mannose and 1 - 30 mM for fructose. The sugar sensor can be used repeatedly after rinsing in 10 mM acetate buffer (pH 4.5).
Journal
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- Analytical Sciences
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Analytical Sciences 20 (5), 757-759, 2004
The Japan Society for Analytical Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390282679233685632
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- NII Article ID
- 10012941180
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- NII Book ID
- AA10500785
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- COI
- 1:CAS:528:DC%2BD2cXkt1ehtL8%3D
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- ISSN
- 13482246
- 09106340
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- NDL BIB ID
- 6938246
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- PubMed
- 15171277
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- Abstract License Flag
- Disallowed