Selective extraction of lithium with a macrocyclic trinuclear complex of (1,3,5-trimethylbenzene)ruthenium(2) bridged by 2,3-dioxopyridine
-
- KATSUTA Shoichi
- Graduate School of Science, Chiba University
-
- IMOTO Takahiro
- Graduate School of Science, Chiba University
-
- KUDO Yoshihiro
- Graduate School of Science, Chiba University
-
- TAKEDA Yasuyuki
- Graduate School of Science, Chiba University
書誌事項
- タイトル別名
-
- Selective Extraction of Lithium with a Macrocyclic Trinuclear Complex of (1,3,5-Trimethylbenzene)ruthenium(II) Bridged by 2,3-Dioxopyridine
この論文をさがす
説明
A macrocyclic trinuclear complex of (1,3,5-trimethylbenzene)ruthenium(II) bridged by 2,3-dioxopyridine was synthesized, and the extraction properties for lithium and sodium picrates were investigated in a dichloromethane/water system at 25°C. The complex was found to have extremely high extractability and selectivity for lithium picrate; the logarithmic values of the extraction constants are 5.86 and 2.63 for Li+ and Na+, respectively. By using this complex as an extractant, nearly quantitative extraction and separation of Li+ from Na+ could be achieved by a single extraction.
収録刊行物
-
- Analytical Sciences
-
Analytical Sciences 24 (10), 1215-1217, 2008
社団法人 日本分析化学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679234377088
-
- NII論文ID
- 10025206602
-
- NII書誌ID
- AA10500785
-
- ISSN
- 13482246
- 09106340
-
- NDL書誌ID
- 9667155
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- 抄録ライセンスフラグ
- 使用不可