Colorimetric Recognition of Different Enzymology-concerning Transition Metals Based on a Hybrid Cluster Complex

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  • LI Shun-Hua
    The Key Laboratory of Analytical Science of MOE and Department of Chemistry, Xiamen University
  • YUAN Wen-Tao
    The Key Laboratory of Analytical Science of MOE and Department of Chemistry, Xiamen University
  • ZHENG Hong
    The Key Laboratory of Analytical Science of MOE and Department of Chemistry, Xiamen University
  • XU Jin-Gou
    The Key Laboratory of Analytical Science of MOE and Department of Chemistry, Xiamen University

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A hybrid cluster complex, formed by chelating a chromogenic ligand to a [2Fe-2S] cluster, sensitively exhibited differential colorimetric responses towards Hg2+, Cd2+, Cr3+, Pb2+, Sn2+, Cu2+, Zn2+, Fe3+ and Co2+ in water at physiological pH. Speciation of some of these metal elements, such as Cr(III) and Sn(IV), was also studied by UV/Vis absorption.

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  • Analytical Sciences

    Analytical Sciences 20 (7), 997-999, 2004

    社団法人 日本分析化学会

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