A PVC Plasticized Sensor for Ni(II) Ion Based on a Simple Ethylenediamine Derivative
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- KUMAR Krishnapillai Girish
- Department of Applied Chemistry, Cochin University of Science and Technology
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- PODUVAL Remalakshmy
- Department of Applied Chemistry, Cochin University of Science and Technology
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- AUGUSTINE Pearl
- Department of Applied Chemistry, Cochin University of Science and Technology
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- JOHN Sareena
- Department of Applied Chemistry, Cochin University of Science and Technology
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- SARASWATHYAMMA Beena
- Department of Applied Chemistry, Cochin University of Science and Technology
Bibliographic Information
- Other Title
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- PVC Plasticized Sensor for Ni 2 Ion Based on a Simple Ethylenediamine Derivative
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Abstract
A new PVC membrane ion selective electrode which is highly selective towards Ni(II) ions was constructed using a Schiff base containing a binaphthyl moiety as the ionophore. The sensor exhibited a good Nernstian response for nickel ions over the concentration range 1.0 × 10-1 - 5.0 × 10-6 M with a lower limit of detection of 1.3 × 10-6 M. It has a fast response time and can be used for a period of 4 months with a good reproducibility. The sensor is suitable for use in aqueous solutions in a wide pH range of 3.6 - 7.4 and works satisfactorily in the presence of 25% (v/v) methanol or ethanol. The sensor shows high selectivity to nickel ions over a wide variety of cations. It has been successfully used as an indicator electrode in the potentiometric titration of nickel ions against EDTA and also for the direct determination of nickel content in real samples: effluent samples, chocolates and hydrogenated oils.
Journal
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- Analytical Sciences
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Analytical Sciences 22 (10), 1333-1337, 2006
The Japan Society for Analytical Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390282679235092736
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- NII Article ID
- 130004441184
- 10018321867
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- NII Book ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL BIB ID
- 8080371
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed