Curing Dynamics of Photopolymers Measured by Single-shot Heterodyne Transient Grating Method
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- ARAI Mika
- Department of Applied Chemistry, Chuo University
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- FUJII Tomomi
- Department of Applied Chemistry, Chuo University
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- INOUE Hayato
- Department of Applied Chemistry, Chuo University
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- KUWAHARA Shota
- Department of Applied Chemistry, Chuo University
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- KATAYAMA Kenji
- Department of Applied Chemistry, Chuo University
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The heterodyne transient grating (HD-TG) method was first applied to the curing dynamics measurement of photopolymers. The curing dynamics for various monomers including an initiator (2.5 vol%) was monitored optically via the refractive index change after a single UV pulse irradiation. We could obtain the polymerization time and the final change in the refractive index, and the parameters were correlated with the viscosity, molecular structure, and reaction sites. As the polymerization time was longer, the final refractive change was larger, and the polymerization time was explained in terms of the monomer properties.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 29 (4), 401-404, 2013
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679238381440
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- NII論文ID
- 10031165329
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- NII書誌ID
- AA10500785
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- COI
- 1:STN:280:DC%2BC3srkt1yitA%3D%3D
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 024405299
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- PubMed
- 23574665
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 使用不可