繊維および繊維高分子材料の無定形領域における分子運動に原因する力学的損失正接(tanδ)‐温度曲線の解析 II  緩和時間が幅広い分布を持つ系

書誌事項

タイトル別名
  • Analysis of Dynamic Loss Tangent (tanδ) -Temperature Curve Relating to Molecular Motion of Polymer Chain in Amorphous Regions in Fibers and Fiber-Forming Polymeric Materials.
  • (第2報)緩和時間が幅広い分布を持つ系

抄録

An attempt has been made to establish the relationships between the distribution Fτ (τ) of relaxation timeτand the shape and characteristic parameters of dynamic loss tangent (tanδ) -temperature (T) curve. For this purpose, the theoretical equation representing tanδ-T curve is derived for ten kinds of function formula for Fτ (τ) : seven functions of which are given by Fτ (τ) =kn'τn' (where, kn' : constant independent ofτ, n'=-2-3) (1), and three functions are given by triangles. WLF and Arrhenius types have been assumed for temperature dependence of τ.On the basis of the theoretical equations derived here, tanδ-T curve has numerically been calculated with the aid of an electronic computer. In the case of n'≥0 in eq. (1), the peak value of tanδ-T curve, (tanδ) max, peak tamperature Tmax, and the ratio of half value width ΔT1/2/ΔT1/2 (s) (the suffix s indicates the system composing of a single relaxation time) depend on the average relaxation timeτ, Fτ (τ), the total number of Maxwell elements in a system N, the ratio of elastic modulus before and after relaxation α, and the minimum relaxation time τl in Fτ (τ).In the case of n'≤-0.5 in eq. (1), the shoulder is significantly observed in the lower temperature region than Tmax in tanδ-T curve. The necessary conditions for appearance of this kind of shoulder is (tanδ) max≥3.5/ (n'+3) 4 and/N≥ √10.The tanδ-T curve (especially, ΔT1/2/T1/2 (s) , mearsured in the temper ature range of apperance of dynamic absorption arising from microbrownian movement of polymer seg ment in amorphous region of semi-crystalline polymers (αa), is remarkably different from that calculated by using the above mentioned functions for Fτ (τ). Contrary to this, tanδ-T curve determined experimentally in the temperature range of αa absorption of amorphous polymer is in fairly agreement with that calculated by using n'=-2-0 in Fτ (τ) =kn'τn' .In the actual experiment, no shoulder is observed in tanδ-T curve,

収録刊行物

  • 繊維機械学会誌

    繊維機械学会誌 30 (3), T55-T65, 1977

    一般社団法人 日本繊維機械学会

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詳細情報 詳細情報について

  • CRID
    1390282679243678464
  • NII論文ID
    130004390035
  • DOI
    10.4188/transjtmsj.30.3_t55
  • ISSN
    18801994
    03710580
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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