超臨界二酸化炭素によるCCA処理木材からの金属抽出の試み 銅・クロムの抽出

書誌事項

タイトル別名
  • Extraction of Metals from CCA-treated Woods by Supercritical Carbon Dioxide. Extraction of Copper and Chromium.
  • チョウリンカイ 2 サンカ タンソ ニ ヨル CCA ショリ モクザイ カラ ノ キンゾク チュウシュツ ノ ココロミ ドウ クロム ノ チュウシュツ
  • Extraction of Copper and Chromium
  • ―銅・クロムの抽出―

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説明

The use of supercritical fluid was tested for the purpose of developing an environmentally benign technique for metal extraction from CCA-treated waste wood. The effects of a chelating agent and extraction conditions on metal recovery were examined experimentally. The recovery for copper and chromium was relatively high but that for arsenic was very low. Metal recovery by pure supercritical carbon dioxide was very low because the affinity between carbon dioxide and metal seemed to be weak. However, it was significantly improved by adding acetylacetone as a chelating agent. The metals in wood were found to be extracted uniformly in all regions of a piece. It was also found that continuous addition of acetylacetone increased metal recovery compared with the one-time addition at the beginning.

収録刊行物

  • 木材保存

    木材保存 26 (1), 17-25, 2000

    公益社団法人 日本木材保存協会

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