Selective Dehydrogenation of Cycloalkanes with Sulfur Tolerant Catalysts
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- FUJIMOTO Kaoru
- Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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- FUKUDA Masaichi
- Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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- TOYOSHI Seiji
- Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
Bibliographic Information
- Other Title
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- 耐硫黄性炭素触媒を用いるシクロアルカン類の選択的脱水素反応
Abstract
Cyclohexane and other alkyl cyclohexanes were dehydrogenated selectively to benzene and alkyl benzenes with active carbon catalysts which supported metals such as vanadium, thorium, copper, cobalt and nickel on it. While metals such as copper, cobalt and nickel lost their original activity almost completely by being sulfided by H2S, they exhibited excellent activities and selectivities when supported on active carbon. Especially, sulfided nickel (Ni (s)) on active carbon showed the best capability as the catalyst. The catalytic activity of Ni (s) on active carbon for cyclohexane dehydrogenation increased with increasing metal content in the catalyst up to 5 wt%. However, above the limit the activity was independent of the metal loadings. The reaction mechanism was explained by the “reverse spillover” mechanism, which comprises the transfer of hydrogen atoms from feed hydrocarbons to carbon surface, the migration of hydrogen atoms from carbon surface to metal or metal sulfide particles on it and the recombination of hydrogen atoms to hydrogen molecules to desorb into gas phase.<BR>The reactivity of mono-alkyl cyclohexane increased with the increase in the molecular weight of them, suggesting the role of van der Waals force in the adsorption of reactant onto active carbon.<BR>The reaction of hydrocarbon mixture which comprises normal hexane and methyl cyclohexane revealed that the dehydrogenation of normal hexane was suppressed markedly while that of methyl cyclohexane was not. The phenomenon are interpreted by that the active sites on carbon are covered by hydrogen from methyl cyclohexane.<BR>It was emphasized by the authors that the present sulfur tolerant catalysts (sulfided metal-active carbon) are favored for reforming coal derived naphtha which containes organo sulfur- and organo nitrogeno- compounds in high concentrations and thus is unsuitable for being treated with the conventional reforming catalysts.
Journal
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- Journal of the Fuel Society of Japan
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Journal of the Fuel Society of Japan 62 (9), 769-774, 1983
THE JAPAN INSTITUTE OF ENERGY
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Details 詳細情報について
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- CRID
- 1390282679298769280
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- NII Article ID
- 130004016487
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- ISSN
- 2185226X
- 03693775
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed