Direct Observation of Intermediates in Sensitization Reaction of Anthracenes and Oxime Type Photoacid Generator in Polymer Matrix
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- Takahara Shigeru
- Graduate School of Advanced Integration Science, Chiba University
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- Nishizawa Naoto
- Graduate School of Advanced Integration Science, Chiba University
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- Tsumita Tomoaki
- Graduate School of Advanced Integration Science, Chiba University
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説明
In the anthracene derivatives (XA) /an oxime type photoacid generator (PAG), (Z,E)-2-(4-methoxy-phenyl)-2-[(4-methylphenyl-sulphonyl)oxyimino]-acetonitrile (PAIOTos) photoinitiating system to give high photosensitivities, radical cations XA.+ were directly observed. It clearly supports that the sensitization mechanism is the singlet electron transfer from XA to the PAG. The XA/PAIOTos system gave higher sensitivity than PAIOTos did in a photopolymer materials.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 22 (3), 289-294, 2009
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詳細情報 詳細情報について
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- CRID
- 1390282679300422400
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- NII論文ID
- 130004464727
- 40016635433
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- NII書誌ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BD1MXoslCisLc%3D
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 10270350
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可