Electrical Conduction of Organic Thin Film with Copper/Thiol-based Self-Assembled Monolayer Anode

  • Mori Tatsuo
    Department of Electrical Engineering, Aichi Institute of Technology
  • Imai Kazuhiro
    Department of Electrical Engineering and Computer Science, Nagoya University
  • Furuhashi Hideo
    Department of Electrical Engineering, Aichi Institute of Technology
  • Nishikawa Takao
    Center for Regional Collaboration in Research and Education, Iwate University

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We have improved lifetime and low driving voltage of the device using an electrode modified by a silane-based fluorinated self-assembled monolayer (FSAM) on ITO (transparent electrode). In the process of fabricating organic light-emitting diodes (OLEDs) devices using Ag or Cu electrode modified by a fluorinated thiol-based SAM, anomalous current saturation phenomena was observed on current-voltage characteristics only when using a thiol-SAM-modified Cu anode. When the performance of the OLED with thiol-SAM-modified Cu or Ag anode were compared with that of the OLED with FSAM-modified ITO, the thiol-SAM-modified Ag anode showed more excellent performance than the FSAM-modified ITO. The OLED with thiol-SAM-modified Cu anode also showed the strange EL efficiency behavior in the saturation current region.

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