In-situ Polymerization of Thiophene Derivatives Using a Gas-phase Oxidant to Form a Hole-transporting Layer in Dye-sensitized Solar Cell
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- Sasada Yoshito
- Department of Applied Chemistry, Waseda University
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- Kato Fumiaki
- Department of Applied Chemistry, Waseda University
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- Oyaizu Kenichi
- Department of Applied Chemistry, Waseda University
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- Nishide Hiroyuki
- Department of Applied Chemistry, Waseda University
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抄録
Poly(3,4-ethylenedioxythiophene) (PEDOT), for use as a hole-transporting layer in dye-sensitized solar cells (DSSCs), was synthesized via in-situ polymerization using a gas-phase oxidant. Highly volatile iodine was used as the gas-phase oxidant to fill up a porous TiO2 substrate. The conductivity of PEDOT increased to 0.9 S/cm upon the addition of a base, 4-tert-butylpyridine, to the monomer solution. A solid-state DSSC was fabricated using PEDOT as the hole-transporting layer, which displayed photo-electric conversion.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 27 (3), 347-350, 2014
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詳細情報 詳細情報について
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- CRID
- 1390282679301665792
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- NII論文ID
- 130004687589
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 025604281
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可