Precise Synthesis of Acrylic Block Copolymers and Application to On-demand Dismantlable Adhesion Systems in Response to Photoirradiation and Postbaking
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- Yamanishi Keisuke
- Department of Applied Chemistry and Bioengineering, Graduate School of Engineering, Osaka City University
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- Sato Eriko
- Department of Applied Chemistry and Bioengineering, Graduate School of Engineering, Osaka City University
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- Matsumoto Akikazu
- Department of Applied Chemistry and Bioengineering, Graduate School of Engineering, Osaka City University
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Abstract
High-molecular-weight and functional acrylic block copolymers containing both the reactive and polar repeating units were synthesized using organotellurium-mediated living radical polymerization (TERP) technique. The block copolymers consisted of poly(tert-butyl acrylate) as the reactive segment and the random copolymer sequence containing n-butyl, 2-ethylhexyl, and 2-hydroxyethyl acrylate repeating units as the adhesive segment. The block copolymers exhibited high performance for the dismantlable adhesion responsible to dual external stimuli consisting of photoirradiation and the postbaking in the presence of a photo acid generator.
Journal
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 26 (2), 239-244, 2013
The Society of Photopolymer Science and Technology(SPST)
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Keywords
Details 詳細情報について
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- CRID
- 1390282679302258944
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- NII Article ID
- 130004465027
- 40019685611
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- NII Book ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BC3sXhtFalu7nK
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- ISSN
- 13496336
- 09149244
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- NDL BIB ID
- 024660405
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed