Low Temperature Film-fabrication of Hardly Soluble Alicyclic Polyimides with High Tg by A Combined Chemical and Thermal Imidization Method
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- Matsumoto Toshihiko
- Department of Life Science and Sustainable Chemistry, Faculty of Engineering, Tokyo Polytechnic University
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- Ishiguro Eriko
- Department of Life Science and Sustainable Chemistry, Faculty of Engineering, Tokyo Polytechnic University
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- Komatsu Shinichi
- Central Technical Research Laboratory, JX Nippon Oil & Energy Corporation,
書誌事項
- タイトル別名
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- Low Temperature Film-fabrication of Hardly Soluble Alicyclic Polyimides with High T<sub>g</sub> by a Combined Chemical and Thermal Imidization Method
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The alicyclic dianhydride having cyclopentanone bis-spironorbornane structure (CpODA) was polycondensated with aromatic diamines at room temperature to give poly(amic acid)s having an inherent viscosity (ηinh) range of 1.3-0.54 dL/g. The poly(amic acid)s were imidized by three methods. The imidization ratio of PI(CpODA+3,4’-DDE) reached 100% at 200 °C using a combined chemical and thermal imidization method. All the polyimide films possessed excellent thermal stability and most of the polyimides had Tg’s over 330 °C. The CTE value of thermally imidized PI(CpODA+4,4’-DABA) was as low as 15 ppm/K. The polyimide films exhibited λcut-off’s shorter than 336 nm, and the Tvis value of each polyimide film was over 85%. Especially, PI(CpODA+3,4’-DDE) prepared by a combined chemical and thermal method had outstanding optical properties (Tvis:88 %, λcut-off’s:278 nm) due to the low temperature film-fabrication.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 27 (2), 167-171, 2014
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詳細情報 詳細情報について
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- CRID
- 1390282679302555264
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- NII論文ID
- 130004678333
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 025604147
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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