Effects of Orientational Relaxation of Polymer Chains Induced by Isotropic Particles on the Enhanced Thermal Conductivity of AlN-filled Polyimide Films
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- Tanimoto Mizuka
- Department of Chemistry and Materials Science, Tokyo Institute of Technology
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- Ando Shinji
- Department of Chemistry and Materials Science, Tokyo Institute of Technology
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A series of composite films composed of μm-sized aluminum nitride (AlN) particles and polyimides (PIs) were fabricated using (a) rigid-chain sBPDA-PPD (sBPPD) PI and (b) flexible-chain sBPDA-ODA (sBPOD) PI as matrices. The relationship between their morphological structures and thermophysical properties were investigated by analyzing cross-sectional SEM images and by measuring out-of-plane thermal conductivity (TC⊥) and in-plane coefficients of thermal expansion (CTE//). The sBPPD chains exhibited a better polymer-filler packing behavior due to their rigid structure having small free volume. Both TC⊥ and CTE// of AlN-filled sBPPD films showed positive deviations from theoretical predictions, whereas no such behavior was observed in AlN/sBPOD composites or in sBPPD films filled with highly anisotropic hexagonal boron nitride (hBN) flakes. The enhanced TC⊥ and CTE// observed for the sBPPD composites can be attributed to a significant change in the orientational state of the PI chains; in-plane orientated sBPPD chains in the pristine PI film become distorted by incorporation of isotropic AlN particles.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 27 (2), 193-198, 2014
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詳細情報 詳細情報について
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- CRID
- 1390282679302564096
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- NII論文ID
- 130004678338
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 025604157
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
- NDL
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- CiNii Articles
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