ポリプロピレンインパクトコポリマーにおける熱酸化劣化挙動と一次構造の関係

  • 中谷 久之
    Department of Bioengineering and Chemistry, College of Environment Engineering and Architecture, Kanazawa Institute of Technology
  • 真鍋 礼男
    Research and Evaluation Center
  • 川村 健一
    Research and Evaluation Center
  • 石川 正尚
    Research and Evaluation Center
  • 鈴木 正太郎
    School of Materials Science Japan Advanced Institute of Science and Technology
  • 寺野 稔
    School of Materials Science Japan Advanced Institute of Science and Technology

書誌事項

タイトル別名
  • Relationship between Thermal Oxidative Degradation Behavior and Primary Structure in Polypropylene-Impact Copolymer
  • ポリプロピレンインパクトコ ポリマー ニ オケル ネツ サンカ レッカ キョドウ ト 1ジ コウゾウ ノ カンケイ

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抄録

In this paper, thermal oxidative degradation was performed using four kinds of polypropylene-impact copolymers (ImPP), and the relationship between degradation behavior and primary structure were inves tigated by 13 C-NMR, GPC and titration of hydroperoxide using potentiometry. It was found that the rate of degradation mainly depended on the ethylene content and did on tacticity in the same content. The information would be useful for synthesis of ImPP having a higher stability.

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